#fema scale
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#talkin#tik tok#food#waffle house#fema#fema scale#worker exploitation#workers rights#union#unionize#ussw#5k#10k#15k#20k
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Must be something like the FEMA Wake House damage scale.
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Monarch: Legacy Of Monsters – Grounded Storytelling Done Well
(This article has been written after the debut of Episode 6 of Monarch: Legacy of Monsters has debuted, titled ‘The Way Out’. This article contains minor spoilers for all the episodes up until this point)
Monarch: Legacy Of Monsters is a show which I have been feverishly excited for since it was first announced as an upcoming project set to debut on Apple TV. As a young boy, I had always enjoyed shows which brought secret organisations to the forefront in fantastic worlds – loving both Agents of S.H.I.E.L.D and the presence of U.N.I.T throughout Doctor Who.
The announcement of this show had me excited for a deep dive into the shady entity known as MONARCH from the films. Would this series expand our understanding of the secret organisation? Would we see more of the Outposts and facilities hinted at in 2014’s Godzilla, and the subsequent Godzilla: King of The Monsters?
Whilst this show has done a fantastic job of exploring who MONARCH are within this universe, it has done something better in my opinion. It has presented us with a grounded, character-driven story within this universe – something I want to reflect on in this piece.
Devastating world events are nothing new. Unfortunately, the world we live in is often shook by devastating events. In films and other creative media, we often see large, grandiose set-pieces which portray this destruction and devastation – but we scarcely ever see the fallout of that havoc. This is where Monarch: Legacy Of Monsters shines.
This series has done a fantastic job of showing us how this world has changed – with small details like posters, graphics and advertisements tying directly into the proliferation of Titans across the Earth, to larger-scale additions like the missile launchers found in Tokyo in Episode 1, or the FEMA resettlement camp and subsequent quarantine area we see in Episode 5.
Not only do these visuals have striking resemblances with our understanding of the real world – the latter particularly provoking images of the aftermath of Hurricane Katrina – but they help to give us, as the audience, a tangible sense of how Titans have changed what the everyday looks like within this world. This lays the foundations for the growth of both MONARCH activity and international collaboration to counter the Titans seen in KOTM.
Alongside this enriching and immersive worldbuilding, we also have deep, emotive stories which directly intertwine the characters who are the vessel for these stories with the events and incidents which have shaped the world in which they inhabit.
Seeing direct, first-person trauma which characters have experienced as a direct result of the events we see on the big screen in the Monsterverse cinematic universe really helps to add emotional weight to these films, and allows much greater insight into how substantial the events we see unfolding on the big screen are.
I have loved seeing how these events have informed so many people’s lives in different ways – leading to our characters making difficult and sometimes dangerous decisions based on their own experiences. This is emotive storytelling done well, and I love how it has become a vessel through which we can explore the real impact that battles of titanic proportions have.
All this is to say – Monarch: Legacy of Monsters is grounded storytelling done well. I love the emotional weight we feel across this story so far, and also have enjoyed seeing how the world has been changed by the G-Day forever. This makes the universe feel real and lived in, and adds so much more depth to the events we see unfolding in Gareth Edward’s film.
Don’t get me wrong – this show IS delivering more about MONARCH. We are beginning to peel back the layers of this mysterious organisation in an exciting narrative which still leaves me with more questions than answers, but for me, the true strength of this series comes in how it creates a world which feels irreversibly changed by Titans.
I hope you have enjoyed this article on a slightly different topic here on The Jurassic Park Podcast. Make sure to check out Brad and I breaking this series down each week on the YouTube channel, and stay tuned for more content in the future!
Written by:
Tom Jurassic
#article#steven spielberg#steven spielberg mattel#mattel creations#mattel creations jurassic park#mattel creations steven spielberg#steven spielberg toy#jurassicworldchaostheory#campcretaceous#jurassicworldchaostheorytrailer
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2/6-12/23
I am so painfully tired, which has translated alternatingly into feelings of both rage and despair this week. It is going to be a long next four weeks.
Anyway, I’ve said before that I love Hitsugaya best when he is being as boring as possible, and this week I really got to luxuriate in that, because in this part of Hinamori’s chapter she is basically letting Hitsugaya talk at her about all of the things that annoyed him about the captain’s meeting just got back from, including:
Central 46’s emergency management strategy
wartime rush-graduated shinigami
the dangai
Mayuri taking about the dangai
Mayuri
Kensei
rice tithes
And what is more gloriously entertaining than thinking about ghost FEMA and uh idk ghost NAFTA? Well, thinking about ghost budget archives, obviously, which is what they spend the NEXT part of the scene doing. Hinamori is a Real One.
Something I’m working out now is how I want to describe the budget annotations. My vision for why these budget sheets are annoying (besides being written by some yahoo 10th captain emeritus from several hundred years ago) is that the language they’re written in is super old school, even by shinigami standards.
I’m basing the way they’re written off of kanbun, which is a way of annotating Classical Chinese, and back in the day was used for poetry translations but also reports, newspapers, etc. as a way of condensing writing. I’m trying not to get too in the weeds about that, because the point is creative verisimilitude, not historical accuracy; this is a GHOST BUDGET SHEET. I just want the shriveled old budgets to be written in a way that is frustratingly not the norm now, for misery’s sake. But I need to decide how I’ll describe that in a way that 1) is true to Hinamori’s POV, since she knows what she’s looking at (mostly) and doesn’t need to belabor the point, but 2) makes enough sense to the audience to not derail anything.
As far as verisimilitude goes, part of me is sitting here refuting my own budget sheet headcanon like "this idea doesn’t work because THEY DEFINITELY STILL WRITE GOTEI REPORTS LIKE THAT. The reports never modernized!" Because, really, why would they? The arguments I can think of in favor of my desires are 1) The SC is written in modern Japanese, 2) I don’t think you can T9 kanbun on a flip phone, Hitsugaya, and 3) they only have *six years* to learn how to be shinigami, how much time are they going to waste teaching these illiterate fucks how to read and write in TWO different forms? (Counterargument: Joe Shinigami has infinite time between grunt work and seated report-writing work to learn kanbun if he wants that sweet promotion.)
Bearing in mind that all this writing system talk is right before Hitsugaya and Hinamori talk about statistical modeling and the way research-based duty release works in the Gotei, so any description of *the history of writing systems in Soul Society* is not entering into this tabula rasa, and there’s already a bunch of off-hand, in-the-weeds Work Talk weighting the scale, LOL.
In any case, Hinamori and Hitsugaya are on the brink of running out of math to talk about, at which point they will have no choice but to talk about feelings. (As though all the math wasn’t also about feelings).
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Emergency Disaster Cleanup Utah - 24 Hour Service | Immediate Response | Fully Licensed and Insured
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When faced with a disaster emergency, finding the best Utah disaster clean up Company for Emergency Disaster Services is essential. They can help with the immediate cleanup needs and also have experience handling large-scale disasters like hurricanes and wildfires.
When a disaster strikes, know that you are not alone. Many businesses offer emergency Disaster Services to help clean up and restore property after an incident. Some tips for finding the best Utah company for your needs:
Do your research – when searching for a Utah Disaster Clean-Up Company, search online or contact local Chamber of Commerce offices for recommendations.
Talk to several companies – it is essential to speak with as many different companies as possible to get a sense of their services and prices. You may be surprised at what you learn!
Consider Licensing and certifications – if professional licensing or certification is essential for you, make sure to inquire about these requirements from each company before making any decisions. These measures can increase trustworthiness and credibility among potential clients.
Get quotes - Once you've interviewed several companies, it's time to get estimates so that there is an accurate picture of what work will need to be done to notarize one contract over another.
Conclusion:
If you are looking for a locally owned, licensed, and insured company in Utah for emergency disaster restoration services, then look no further than Serveantage. We are here to help you with your needs 24 hours a day and 7 days a week. Our disaster restoration experts have the skills and experience to handle any type of emergency disaster situation that may occur.
Emergency Disaster restoration services in Utah is able to help with water damage restoration, fire damage restoration, mold remediation and removal, storm damage cleanup, as well as other types of disasters that may occur in the state of Utah. Call us today at (385) 350-4064 or visit our website at www.serveantage.com to learn more about our company!
#Utah#utah restoration service#utah disaster cleanup#emergency plumber carlingford#disaster restoration services#restoration services#water damage restoration utah
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Hurricane Prep and Guide
Hey all! I thought I'd make a list for Floridians as a guide/checklist of things to prepare for with Hurricane Ian. Preparation is extremely important and if you haven't prepared yet, do it now! If you've already prepared, that's great! But included are things you should know, should do just in case, and think ahead. And this is coming from someone who weathered Hurricane Michael in 2018, so this information isn't coming from an outsider or someone with only Google as their resources. This is from personal experience, research, and official information that helped me survive a Category 5 hurricane. Don't follow this word for word, but use it as a reference, resource list, and guide for anyone unfamiliar with hurricanes or stranded for the hurricane!
Terminology
Baker Act: A Florida-specific law that allows doctors, mental health professionals, judges, and law enforcement to commit a person to a mental health treatment center for up to 72 hours if they display certain violent or suicidal signs of mental illness. It is common in the aftermath for a significant uptick in Baker Acts as emotions run high and mental health declines severely after natural disasters.
Category/Categories: A form of organizing a hurricane dependent on its sustained winds. This scale is between 1 and 5, with 1 being the least powerful and 5 being the most powerful.
(Evacuation) Zones: During evacuation, people are evacuated by zones. Zones that are listed from Tropical Storm, Zone A, Zone B all the way to Zone E and Zone F. Tropical Storm Zone and Zone A are the most vulnerable (and thus are evacuated first) whereas Zones E and F are the least vulnerable and evacuated last. Only four NE counties of FL use Zone F so usually the zoning ends at Zone E.
DOA: Dead on Arrival. The person in a house is expected/found dead.
Eye Wall: The outside ring surrounding the eye. Generally the most destructive as wind and rain is more intense here than anywhere else in the hurricane. The "right-front" quadrant of the eye wall is the most destructive part and sometimes referred to as the "dirty side".
Eye: The center of a hurricane. This part is calm as there's no high wind or water. The eye is generally around 20-40 miles long and will take 30-45 minutes to pass over. This can be dangerous as people assume the hurricane is over and go outside. You can tell if you're in the eye since it's surrounded by a wall!
FEMA: Federal Emergency Management Agency. Each state has a FEMA branch that oversees general recovery and preparation efforts. They also work with insurance companies on designations for natural disasters. People usually go to FEMA for resources such as monetary aid, shelters (Permanent and temporary), and general information.
Go North: Florida news and locals will refer to evacuation as "Going North". This is because to evade hurricanes, people usually go further inland where hurricanes dissipate into storms/tropical storms rather than any other direction where it could turn and hit you elsewhere.
Hurricane/Tropical Storm Warning: Conditions for a hurricane/tropical storm is imminent and expected.
Hurricane/Tropical Storm Watch: Conditions for a hurricane/tropical storm are favorable and expected, but not occurring or imminent.
Hurricane: An organized rotating storm above 74 miles. Usually with low-pressure, strong winds, and a circular arrangement of thunderstorms (or arms/bands) commonly found around the Gulf Coast and the Carribean.
Limit: During hurricanes, items like water, food, ice, and other miscellaneous items have a limit per person. Publix at Orlando has a limit on water to "4 per person" to ensure everyone has enough water or a chance to get water.
Looters: People who have come to a natural disaster area and steal items. Very common after hurricanes.
Major Hurricane: A hurricane above Category 3. Major hurricanes get more attention as that means they pose significant risks and dangers.
Martial Law: An instance where the military takes control of the area. In terms of hurricanes, this usually means the National Guard takes control, enforces a curfew, and prevents looting.
NOAA: National Oceanic and Atmospheric Administration. They are a federal agency that monitors and provides updates/forecasts on hurricanes and other related things.
National Guard: The National Guard are a part of the military equipped to handle natural disasters. They aid in ethe vacuation, preparation, and aftermath procedures. They are usually armed but are friendly. They also enforce martial law.
Outer Bands: Also called rain bands or arms! This part of the hurricane is not as destructive but has a tendency for thunderstorms and even tornadoes!
Personnel: Throughout this post, I will reference "personnel". Personnel are people who work at shelters and are on the frontline of hurricanes helping those affected. This can include volunteers, the Red Cross, and National Guard, amongst others.
Pop-up Shelter: A last-minute shelter to deal with an influx of affected people.
Pressure: A measure of molecules in the air. The lower the number, the stronger a hurricane since low pressure increases the wind speed and strength of a hurricane. If the pressure starts increasing, the hurricane could be losing strength or reorganizing. If the pressure is decreasing, a storm is forming/approaching and strengthening.
Price Gouging: A predatory tactic by companies to prey on affected people. This is common with gas, food, water, and lodging. This is illegal and should be reported!
Projectiles/Missiles: Projectiles, or missiles, are pieces of debris that's flung by the hurricane at high speeds. This can include chairs, umbrellas, metal, and even cars or trees. At fast enough speeds, anything can be a projectile. A very dangerous hazard during a hurricane.
Red Cross: The Red Cross is an organization that aids in hurricane preparation and recovery. There are others like them but they were the biggest support organization that helped and usually are the biggest to help in hurricanes.
Shelters: Places that are built to withstand hurricane-force winds. Usually equipped with personnel, food, water, and are stronger than a house.
Stagnant Water: Water that hasn't moved in 24 hours. It's a hazard as bacteria, mold, and animals/insects. Stay away!
State of Emergency: A government procedure where normal activity is suspended in preparation/recovery of a natural disaster. Can be county-specific or state-wide.
(State) Officials: Officials are those in government positions who enact, enable, and support citizens affected. Usually, state officials are the ones coordinating support efforts after hurricanes. However, officials can include federal officials such as Congressmembers and the President if a hurricane is disastrous enough. For Florida, a state official is DeSantis as he declared "State of Emergency", works with county and federal officials for support, and delegates other departments to cleanup/recovery efforts.
Storm Surge: A swell of water from storms that have tsunami-like tendencies. These occur on the coast of cities and usually contribute to the most deaths.
(Sustained) Wind Speed: How fast wind is generally moving in an area. This is the usual and overall speed, not to be confused with wind gust!
Tropical Storm: An organized storm with sustained windspeeds between 39-73 miles per hour listed below a Category 1 hurricane. Not as destructive as hurricanes but can be devastating in areas with poor infrastructure.
Turning: A hurricane has a possibility of turning. It usually turns East or West. Hurricanes are unpredictable and can turn either direction without notice or reason. Be on the look if you're on the West Coast.
Wind Gust: A sudden and brief increase of wind. Doesn't last for long but more destructive.
Wind Shear: A change of wind speed in a direction, typically vertical.
X'ed Houses: After a hurricane, houses will be X'ed. Personnel will go door to door to find survivors and will mark houses accordingly.
Category/Categories: A form of organizing a hurricane dependent on its sustained winds. This scale is between 1 and 5, with 1 being the least powerful and 5 being the most powerful.
Major Hurricane: A hurricane above Category 3. Major hurricanes get more attention as that means they pose significant risks and dangers.
Tropical Storm: An organized storm with sustained windspeeds between 39-73 miles per hour listed below a Category 1 hurricane. Not as destructive as hurricanes but can be devastating in areas with poor infrastructure.
Storm Surge: A swell of water from storms that have tsunami-like tendencies. These occur on the coast of cities and usually contribute to the most deaths.
Outer Bands: Also called rain bands or arms! This part of the hurricane is not as destructive but has a tendency for thunderstorms and even tornadoes!
Eye: The center of a hurricane. This part is calm as there's no high wind or water. The eye is generally around 20-40 miles long and will take 30-45 minutes to pass over. This can be dangerous as people assume the hurricane is over and go outside. You can tell if you're in the eye since it's surrounded by a wall!
Eye Wall: The outside ring surrounding the eye. Generally the most destructive as wind and rain is more intense here than anywhere else in the hurricane. The "right-front" quadrant of the eye wall is the most destructive part and sometimes referred to as the "dirty side".
Pressure: A measure of molecules in the air. The lower the number, the stronger a hurricane since low pressure increases the wind speed and strength of a hurricane. If the pressure starts increasing, the hurricane could be losing strength or reorganizing. If the pressure is decreasing, a storm is forming/approaching and strengthening.
Looters: People who have come to a natural disaster area and steal items. Very common after hurricanes.
Martial Law: An instance where the military takes control of the area. In terms of hurricanes, this usually means the National Guard takes control, enforces a curfew, and prevents looting.
Shelters: Places that are built to withstand hurricane-force winds. Usually equipped with personnel, food, water, and are stronger than a house.
Pop-up Shelter: A last-minute shelter to deal with an influx of affected people.
Stagnant Water: Water that hasn't moved in 24 hours. It's a hazard as bacteria, mold, and animals/insects. Stay away!
DOA: Dead on Arrival. The person in a house is expected/found dead.
X'ed Houses: After a hurricane, houses will be X'ed. Personnel will go door to door to find survivors and will mark houses accordingly.
Hurricane/Tropical Storm Watch: Conditions for a hurricane/tropical storm are favorable and expected, but not occurring or imminent.
Hurricane/Tropical Storm Warning: Conditions for a hurricane/tropical storm is imminent and expected.
Price Gouging: A predatory tactic by companies to prey on affected people. This is common with gas, food, water, and lodging. This is illegal and should be reported!
Limit: During hurricanes, items like water, food, ice, and other miscellaneous items have a limit per person. Publix at Orlando has a limit on water to "4 per person" to ensure everyone has enough water or a chance to get water.
FEMA: Federal Emergency Management Agency. Each state has a FEMA branch that oversees general recovery and preparation efforts. They also work with insurance companies on designations for natural disasters. People usually go to FEMA for resources such as monetary aid, shelters (Permanent and temporary), and general information.
NOAA: National Oceanic and Atmospheric Administration. They are a federal agency that monitors and provides updates/forecasts on hurricanes and other related things.
Wind Shear: A change of wind speed in a direction, typically vertical.
Wind Gust: A sudden and brief increase of wind. Doesn't last for long but more destructive.
(Sustained) Wind Speed: How fast wind is generally moving in an area. This is the usual and overall speed, not to be confused with wind gust!
Projectiles/Missiles: Projectiles, or missiles, are pieces of debris that's flung by the hurricane at high speeds. This can include chairs, umbrellas, metal, and even cars or trees. At fast enough speeds, anything can be a projectile.
Baker Act: A Florida-specific law that allows doctors, mental health professionals, judges, and law enforcement to commit a person to a mental health treatment center for up to 72 hours if they display certain violent or suicidal signs of mental illness. It is common in the aftermath for a significant uptick in Baker Acts as emotions run high and mental health declines severely after natural disasters.
Turning: A hurricane has a possibility of turning. It usually turns East or West. Hurricanes are unpredictable and can turn either direction without notice or reason.
State of Emergency: A government procedure where normal activity is suspended in preparation/recovery of a natural disaster. Can be county-specific or state-wide.
Go North: Florida news and locals will refer to evacuation as "Going North". This is because to evade hurricanes, people usually go further inland where hurricanes dissipate into storms/tropical storms rather than any other direction where it could turn and hit you elsewhere.
(State) Officials: Officials are those in government positions who enact, enable, and support citizens affected. Usually, state officials are the ones coordinating support efforts after hurricanes. However, officials can include federal officials such as Congressmembers and the President if a hurricane is disastrous enough. For Florida, a state official is DeSantis as he declared "State of Emergency", works with county and federal officials for support, and delegates other departments to cleanup/recovery efforts.
Personnel: Throughout this post, I will reference "personnel". Personnel are people who work at shelters and are on the frontline of hurricanes helping those affected. This can include volunteers, the Red Cross, and National Guard, amongst others.
Red Cross: The Red Cross is an organization that aids in hurricane preparation and recovery. There are others like them but they were the biggest support organization that helped and usually are the biggest to help in hurricanes.
National Guard: The National Guard are a part of the military equipped to handle natural disasters. They aid in evacuation, preparation, and aftermath procedures. The are usually armed, but are friendly. They also enforce martial law.
(Evacuation) Zones: During evacuation, people are evacuated by zones. Zones that are listed from Tropical Storm, Zone A, Zone B all the way to Zone E and Zone F. Tropical Storm Zone and Zone A are the most vulnerable (and thus are evacuated first) whereas Zones E and F are the least vulnerable and evacuated last. Only four NE counties of FL use Zone F so usually the zoning ends at Zone E.
Should I Evacuate or Stay?
You should listen to the local authority. You can usually find a list of places to evacuate from and where to head. If you choose not to evacuate, please head to shelters that will be set up in your county and region at bare minimum. It will provide you with more security and resources initially.
For those on the coast, I highly recommend it. Homes and similar buildings can only withstand so much and building codes aren't always followed. It's better to go to a shelter where they have staff/resources/the ability to deal with extreme weather. Storm surge is no joke and can sweep away cars and other items.
If you can evacuate, follow an evacuation route where personnel will be directing evacuation efforts. Make sure you have gas and everything below packed and ready. Be aware of price gouging. It's Florida law that hotels, stores, and gas companies cannot price gouge during a natural disaster. If you suspect someone's price gouging, call 1-866-966-7226.
If you can't evacuate, still begin preparations and consider going to a shelter! It will provide you with more security and extra resources that your home may not be able to provide.
Preparation
No matter the situation, you must prepare. It's better to be ready for a possibility than to be caught off-guard and scrambling. Below are things you need to have ready/safeguarded:
Important documents: Birth certificates, IDs, pet records, insurance documents/records, social security cards, licenses, passports, vehicle titles and registration, deeds, financial records, and wills. Anything relating or similar should be taken as well.
Water: At least a gallon per day per person; government recommends at least 3 days worth but I recommend 5. You will be using this not just for drinking but for bathing, medical, and for food. It never hurts to have enough
Food: Canned food (Have can openers to open them), non-perishable items, snacks, and sports drinks. Anything that is not going to be refrigerated and is low-effort.
Cash: Make sure to have enough cash out of the bank! I can't recommend specifically how much but you should take out as much as you're willing to take and lose. Banks will be closed, ATMs and credit/debit cards will not work, and money will be scarce to withdraw. Having money on hand will avoid this situation and you will have the ability to actually buy things if needed. However, be prepared to lose it. Looters and other criminals will be around.
Contact Information: Family, friends, coworkers/employers, schools (for parents or college students), and landlords/management companies. Also have emergency contacts such as local police, firefighters, emergency personnel, and the likes.
Home: Bring in things that are outside. Everything becomes a projectile and you most likely won't get it back. Plants, grills, toys, and yard items. Anything needs to be inside or tied down/secured! This link will provide you a great checklist of things to do. If you are in something that isn't a home/apartment (Like an RV or similar), make sure to turn off propane, put in your slides, and tie EVERYTHING down! I highly suggest you go to a shelter or similar!
Power banks/Electronics: Prepare ANYTHING with a battery. Charge your batteries. Have phones charged before leaving, charge power banks, anything that has an electric signal charge it. This will be important for communication and entertainment.
Radios: Have a radio ready. I personally recommend a crank radio. Make sure that it can run off of batteries or a crank because plugs are a no-go!
Batteries: Any kind of batteries you may need. For flashlights, radios, and others, you want to make sure it'll last long enough until power's back, which can vary location to location.
Lighters/Firewood/Charcoal/Matches: Have ANYTHING that can start a fire. Lighters and matches for the initial lighting. Charcoal/Firewood for the fire. Lighter fluid and starters to actually maintain the fire. You'll want fire for cooking, boiling water, and the likes.
Candles: For light in your home/place of living. Once the hurricane passes, you won't have power so no light. You don't want to waste your phone battery and flashlights. Candles are an easy and useful for night-time lighting indoors.
Flashlights: For walking with lights and to not drain your phone battery.
Clothes: Don't overpack. Have flip-flops, boots, and sneakers ready. It can be horridly hot after a hurricane so pack lighter clothes for the day and a hoodie/pants if you are outside at night.
Ear plugs: The pressure will be killer. Ear plugs will mitigate that by just a bit. However, here's a link on popping your ears if the pressure is unbearable.
Pet/Child supplies: Have pet food, medications, and maintenance items. Same for children. Any toys is HIGHLY recommended. You must have a crate/enclosure for your animal if you are going to a shelter.
Toiletries/Hygiene Items: Feminine products, toothbrushes, soap, and towels will be your friend. I also recommend shaving cream, razors, and deodorant. That will help with any discomfort.
Medication: Make sure you have at least 2 weeks' worth of medication. Hospitals and pharmacies will be looted and destroyed so there's an unlikely chance of getting medication after a hurricane.
Windows: This is a big one. Board them if you can. Storm shutters are your friend! But DO NOT TAPE YOUR WINDOWS! Taping your windows can prevent them from shattering into shards, but that's not great! Larger pieces mean a bigger threat!
Trees: If you are able, cut trees down. Loose limbs will come flying off as missiles and can fall on your house if they're not strong/with roots.
Things I personally suggest and recommend (If you have the time!)
Put things up: Take anything you can't fit in your car (if you're going to a shelter) and put it high up. Water can and will flood through vents and cracks and you are extremely susceptible to flooding if you're in a flood zone. Take everything off your desk/floor/lower shelves and put it all up. This makes it less of a target for looters and keeps it safe from any water damage. I recommend putting them in trash bags as well to further prevent any damage!
Entertainment: Have entertainment ready. Books are a personal recommendation. Download music, movies, shows, and the likes for when you aren't without power because that doesn't mean service is immediate.
Cameras: If you have a phone, that can work too. But a camera will reduce the drain on your battery. This is for insurance purposes. Take pictures of EVERYTHING beforehand and after to prove the hurricane's damage.
Comfortable items: Blankets and pillows especially. You won't have a bed to sleep on, especially in a shelter, and you might be sleeping in a car. Surprisingly, pillows were one of the most sought items after Hurricane Michael, so trust me on this.
Plastic bags: Like the ones you get from grocery stores! Have them on hand. We used them to poop in since there was no running water to flush toilets.
Tools: Wrenches, hammers, screwdrivers, and anything non-power will help you after the hurricane. You may need to jerry-rig something together. You might need to dismantle debris into parts. Tools will help you with anything and everything.
Shelters
Some information may apply for those staying at home!
Shelters can vary on the resources, location, and staffing needs. They may have cots, food, and water, but some will be supplied more and others not. Go to a shelter to ensure you get the resources you need before they run out. Be aware that not every shelter functions the same way! If you have a pet, they will require you have records or else you will be turned away. Drugs and alcohol will not be permitted.
Finding a Shelter: Call the shelter to make sure there's space and it's the right shelter for you. Do you have special needs and need transport? Is the shelter at capacity? What do they recommend you bring? What can you not bring?
At the Shelter: Once you arrive, you check-in. This is either with FEMA/Red Cross and is to make sure that they have a head count and are able to identify any injured/dead so that way there's not any missing. If a loved one contacts them, they may be able to direct you to your location as well. Pets may be placed in another location away from you. This is to prevent irritation to anyone with pet allergies and the like.
Settling Down: Have your documents, some food and water, and other belongings ready. Do not take more than you can carry! Leave any other items in a car but make sure they're well-prepared. Have items in trash bags/containers in case your windows break
Talk with People: Establishing a connection with people will help you gain information. You may be in a hallway/room with other sheltering people and no personnel so these will be your friends for the time being. Exchanging stories, discussing the hurricane, and playing games is encouraged! Just be careful of giving out any personal information like a complete address, full names, and other pieces of information.
Hunker Down: Once the hurricane has made landfall, any and all doors and windows will be closed and locked. You will not be able to leave for any reason. You won't be able to go smoke, use the restroom, or anything. The wind will pick you up, you can be torn to shreds by the missiles, and you could endanger the lives of other people while you're there.
Be Courteous: Try not to take your emotions out on people that are there. Everyone is there going through the same thing you are. The people that are staff are trying to help you. Don't be rude, try to think of others, and just be mindful that you're all in this together. It'll be okay.
The Eye: The eye might pass over and if it does you might be let outside temporarily. Smokers will take a smoke break, people will relieve themselves (If you made a makeshift toilet, dump out the contents!), and people will go outside to breathe. DO NOT STRAY FAR FROM WHERE YOU ARE THOUGH! The eye will pass over and you will be under fire once again. You will have to go back inside, lock up, and sit out the remainder of the eye. Get ready to go back inside in a calm, orderly fashion, and be mindful of your valuables if you leave them for whatever reason.
Aftermath: Once the second part of the hurricane is over, you will still be told to stay put temporarily. Hurricanes can spawn tornadoes and so you will want to be cautious for a few hours once you're out. In the next coming hours, stay put and just gather yourself. Nothing's going anywhere and your safety is #1.
At this point, you will have many options open to you. You can go home, you can evacuate out of town if you feel the need, or you could stay if you don't have the option to return. Pet owners may be forced to leave the following day so be mindful of that. In any case, listen to the personnel there and go off what you know and have. There's no right or wrong choice, just making comfortable and safe decisions.
Hurricane Landfall
FOR PEOPLE IN THE PATH!
You're in the hurricane. Wherever you are, stay put. Listen to the radio if you can for updates. The pressure will be horrible on your ears.
If you stay home, stay downstairs in an interior room without windows. If you are in higher levels, you can risk the roof being torn off and exposed (Yes, this is a strong possibility!). Stay away from windows if possible. Windows will shatter inside, blasting in water and debris, so be sure to block any vents and windows. Closets and bathrooms are recommended. I recommend the bathroom so you have all your belongings in there, get in the tub with a phone, and put a mattress on your body while in the tub. Have an ID on hand so you can be identified if something were to happen.
Have a make-shift toilet at the ready. At the shelter, we used trash cans and buckets we found, made privacy screens with collected towels/blankets, and emptied them during the eye and afterward. Be warned, it will smell awful, but there won't be any running water. Have toilet paper ready!
BE AWARE OF TORNADOES! Tornadoes usually spawn off of the outer bands but can spawn near the eye. People will think they are fine once the hurricane passes, but you must be mindful of any stray tornadoes. If you are not in a shelter, wait a bit longer in your house.
When the hurricane hits, do not leave if everything is calm! It could be a false alarm with the eye passing over. Wait until you hear the all-clear from your radio/personnel. If you are unable, wait for 45 minutes and go outside but examine the sky. Are there tornadoes or a wall? If not, you should be in the clear.
Aftermath
The hurricane itself is disastrous but the aftermath can be just as bad. However, there are different steps you should take initially. For those that didn't evacuate, you will need to gauge your surroundings and choose your choices carefully. Trust your instincts, be careful of strangers, and be aware of your surroundings.
You will be surrounded by danger. Do not approach stagnant water, keep your eyes out for downed powerlines and debris, and be very aware of your surroundings as looters and criminals are on the prowl. The aftermath brings out the worst in people.
Do not drive if you are unsure of yourself and are semi-safe where you are. If you struggle mentally or with driving, you risk popping a tire (debris), losing gas (there's no gas anywhere), and even getting hurt (debris and looters). Make sure everything is secure before leaving. This will be mentally taxing as danger can be anywhere, places you know destroyed, and driving is just stressful in general. Whatever choice you make is the right one, but prepare yourself for any drive period.
IF YOU ARE AT A SHELTER
Most of the time, FEMA, the Red Cross, and military personnel will be there. You will be able to get some information about conditions, appropriate actions, and how to go about things. People with pets may be told to leave so be prepared!
It's going to get crowded from other people coming in from downed homes. If you feel like you are comfortable, head home, but be careful. Just listen to what others are saying but instead of asking about specific streets, ask for community names since they won't be able to give a definite answer but will be able to provide better information if you give a general area! But be mindful as you may not be able to leave immediately. Ask the officials if you are able to leave town to go North since you may be under martial law or there are blockades into/out of town.
If you decide to leave for home, continue below.
IF YOU ARE AT HOME
If you stayed at home, be very mindful of hazards. Live wires from downed powerlines, stagnant water, and dangerous debris are everywhere. Go to a shelter if you think it'll be better but be mindful. There's going to be a lot of people that are already established and others that are like you going for shelter.
If your home is standing strong, is stable, and relatively safe, I'd stay put and begin cleaning up. If your roof is exposed, there's structural damage to multiple walls, or significant debris in your home/area, you will benefit from leaving.
Check on neighbors, survey the area (be mindful of hazards!), and check your home/personal items. See if you have service or what the situation is for your area. Take pictures of damages to your home, vehicle, and other items that are insured before touching anything.
IF YOU ARE EVACUATED
Keep an eye out for news because chances are, you might not be able to return immediately. Officials usually close down roads going to a disaster zone to allow clean-up crew in first and to prevent looters. Unless you have special access, you won't be able to return, you will be turned away. Again, this is to prevent looters.
Make contact with any landlords or property management companies if you are renting from one/work with one. Contact employers as they may have stayed behind for the business as a skeleton crew. Contact other official personnel (Not emergency!) if you are able to return or a date for return.
WHAT TO EXPECT IN THE COMING WEEKS
Martial law could last from days to weeks in certain locations. Hospitals and emergency services will be sent outside of the hurricane's path to open/equipped hospitals. If you are found incapacitated in any way, mentally or physically, you will be transferred to a health facility which could be out of town or even out of the state if there are significant injuries/hospitals are overloaded.
There will be food trucks from people like the Mercy Chefs and similar that will drive through neighborhoods and will pop up in familiar places. Try to get addresses and locations of any places with resources concerning food, water, and other supplies. Food and water don't last forever! Collect what you can but don't hoard.
Be mindful of your gas. There won't be any gas stations open for miles and you will experience a gas drought. If you decide to leave town, just be sure you are taking a route that has gas, you are guaranteed to get from point A to point B, and have backup routes in case of hazards.
Electricity and water will come back in stages. Some locations will get it quicker than others and it won't be all at once. People have said that they received electricity and water days after a hurricane whereas some went without months. No electricity means that appliances won't work, like your fridge. DO NOT OPEN YOUR FRIDGE! This keeps the food from spoiling that's inside. The fridge lasts for 4 hours after power outage and the freezer for 48 hours.
Clean your home if you are staying. Have respirator masks if your home was water damaged and has grown mold. You can treat mold with bleach but be very mindful and careful since it might not work but it is worth a try to mitigate the situation.
Looters and criminals will be roaming for a while! There will be "You loot, we shoot" signs up. Take heed to those signs. People will scam you, steal from you, and likewise so try to stick with people that you are familiar with or are in a safe situation.
Lastly, be there for the community. After Hurricane Michael, Bay County came together on every scale and level possible. From as big as other states to as small as neighbors, we made connections with people and that community gave us hope and care for the future ahead. Give people extra if you have extra. Direct people to FEMA and resources. Be there for each other and you will come out of it stronger than ever!
For People Not in the Hurricane
Please do not joke about the situation. People will lose their lives and livelihoods. Please circulate any information regarding Hurricane Ian relief and efforts. Victims and survivors are forgotten after a week or two so circulating information regarding hurricane relief, efforts, and updates is important so those affected retain the help that they need!
The biggest help wasn't just FEMA or the Red Cross but others who went out with supplies. Consider donating food or items if there's a drive in your area or even start one! The encouragement, help, and aid of others from around the country makes all the difference so please consider donating, volunteering, or even just sharing information to help others that need it!
Resources
Water calculator: A calculator for determining how much water you need per person and for pets!
CNN Updates: A comprehensive list of updates for those who want to read updates (I personally HATE videos). Included are evacuation details, forecasts, and general updates.
Florida Government Updates: A comprehensive list of official updates and happenings with Floridian officials/departments. CURRENTLY UPDATED FROM SEPT 26, 2022!
FEMA: This link will take you directly for Hurricane Ian support and resources. In English and Spanish.
NOAA: This will keep you updated with the most current path of Hurricane Ian.
Price Gouging: This website provides you with information on price gouging, how to go about price gouging, and similar.
Evacuation Routes and Storm Surge Maps by County: The evacuation routes are listed by county. The list may include "Zones" which are listed
Flood Zone Map: Are you in a flood zone? Input your address here and it will give you a look at your surroundings (This is a FEMA resource so don't worry about putting in your address!)
Final Note
If I missed a point, you can reblog with your input! If you have any questions, my ask box is open and I can advise or at least give you the right resource. Please be patient and mindful as I am also preparing for the hurricane and at minimum, the tropical storm.
This isn't something to freak out over, but it is something to take seriously. This can be life or death if you don't prepare since there comes a point where minutes and seconds matter. Maya Angelou once said "Hoping for the best, prepared for the worst, and unsurprised by anything in between.' For this situation, you're preparing for the worst, hoping for the best, and will be pleasantly surprised when it all turns out if you prepare! Good luck and stay safe, everyone!
#hurricane#hurricanes#hurricane ian#ian#resource#long post#natural disasters#hurricane help#hurricane preparation
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So depending on the scale of the ear extreme the earthquake the more aftershocks you will have and the more severe each aftershock will be...
In general, aftershocks are most severe and happen more frequently in the hours and days that follow an earthquake. Larger earthquakes tend to produce larger aftershocks.May 4, 2024
https://www.britannica.com › science
Aftershock | Geology, Earthquake Effects & Prediction - Britannica
Yes, larger earthquakes tend to have more and larger aftershocks that last longer than smaller earthquakes. A large earthquake can have hundreds to thousands of aftershocks that can be detected by instruments. The stress change caused by a large earthquake is thought to be the main reason aftershocks happen. Aftershocks often occur where two types of stress act on a fault change: normal stress and shear stress.
Stanford Doerr School of Sustainability
After the Big One: Understanding aftershock risk | Stanford Doerr School of Sustainability
Sep 21, 2018
FEMA's Preparedness Community
Earthquake | What
Britannica
Aftershock | Geology, Earthquake Effects & Prediction - Britannica
May 4, 2024 — Larger earthquakes tend to produce larger aftershocks. When attempting to predict the decrease in moment magnitude (the measure of the total amount of energy released during an earthquake) between the principal earthquake and the largest aftershock, seismologists often refer to Båth's Law, which notes that the average difference in size between the two events is 1.2 orders of magnitude. The actual difference in size, however, ranges from 0.1 to 3 orders of magnitude. Small aftershocks occur with a greater frequency than large ones; however, aftershock frequency falls off with the passage of time. Notable aftershocks.
en.wikipedia.org
Aftershock - Wikipedia
Large earthquakes can have hundreds to thousands of instrumentally detectable aftershocks, which steadily decrease in magnitude and frequency according to a consistent pattern. In some earthquakes the main rupture happens in two or more steps, resulting in multiple main shocks.
Aftershocks decrease in magnitude and frequency over time, but their magnitudes don't necessarily get smaller. Seismologists sometimes use Båth's Law to predict the difference in size between the main earthquake and the largest aftershock. Båth's Law states that the average difference in size is 1.2 orders of magnitude, but the actual difference can range from 0.1 to 3 orders of magnitude.
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Residents in Conroe's River Plantation Community Rebuild After Flooding for 2nd Time This Year
Devastating Floods Leave Communities in Southeast Texas Struggling to Recover
In the wake of historic flooding that swept through southeast Texas, residents in Conroe's River Plantation community are facing the daunting task of rebuilding their homes for the second time this year. The floods, which have caused widespread damage across the region, have left families devastated and struggling to recover. As the waters recede, the true extent of the destruction is becoming evident, with hundreds of homes destroyed and countless lives upended.
This article explores the impact of the floods on the River Plantation community and the resilience of its residents as they face the arduous process of rebuilding.
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A Trail of Destruction: The Aftermath of the Floods
The floods that hit southeast Texas have left a trail of destruction in their wake. Preliminary counts reveal that over 115 homes have been impacted in Houston and Harris County alone. However, the northern and eastern communities have been hit even harder.
In San Jacinto County, more than 1,000 homes have been flooded, while in Montgomery County, officials estimate that over 500 homes have been damaged. The River Plantation community in Conroe has been particularly hard hit, with 200 out of 1,400 homes destroyed.
For many residents, the devastation is compounded by the fact that they had only recently rebuilt their homes after the floods in January. Now, they find themselves facing the daunting task of starting over once again. The emotional toll of losing cherished possessions, family photos, and treasured mementos is immeasurable.
The resilience and determination of the community, however, remains unwavering.
Stories of Loss and Resilience
Vanise Dunn, a resident of River Plantation, shares her heartbreaking experience of losing her newly rebuilt home to the floods. She recounts the pain of seeing her family's belongings, including cherished decorations and brand-new furniture, destroyed by the rising waters. Dunn's story is just one of many in the community, as families grapple with the devastating impact of the floods.
Despite the immense challenges they face, residents like Dunn are determined to rebuild and restore their lives. Many have expressed gratitude for the outpouring of support from neighbors, friends, and even strangers, who have come together to lend a helping hand. The sense of community and resilience is evident as residents work tirelessly to salvage what they can and start the rebuilding process.
The Need for Assistance and Support
The scale of the damage caused by the floods underscores the urgent need for assistance and support. Many families have lost everything and are in dire need of resources to help them rebuild their lives. The Federal Emergency Management Agency (FEMA) has been on the ground, conducting damage assessments and providing aid to affected communities.
However, the road to recovery will be long and challenging.
Residents in the River Plantation community and other affected areas are encouraged to reach out to FEMA for support. Additionally, local organizations and volunteers have rallied together to provide assistance, including shelter, food, and supplies, to those in need. The spirit of solidarity and compassion is a testament to the resilience of the community.
Looking Ahead: Rebuilding and Recovery
As the floodwaters recede and the recovery efforts begin, the residents of River Plantation and other affected communities face a long and arduous journey. The process of rebuilding homes and lives will require time, resources, and unwavering determination. However, the strength and resilience displayed by the community thus far provide hope for a brighter future.
While the road to recovery may be challenging, it is important to remember that the spirit of community and support will guide residents through this difficult time. The bonds forged in the face of adversity will serve as a foundation for rebuilding stronger, more resilient communities.
The devastating floods that have struck southeast Texas have left a lasting impact on the River Plantation community in Conroe. Residents who recently rebuilt their homes after the floods in January now find themselves facing the daunting task of starting over once again. The emotional toll of losing cherished possessions and the physical toll of rebuilding are immense.
However, the resilience and determination of the community shine through as neighbors come together to support one another.
As the recovery process begins, it is crucial for residents to receive the assistance and support they need to rebuild their lives. Organizations like FEMA and local volunteers have stepped up to provide aid, but the road to recovery will be long and challenging. Despite the hardships, the residents of River Plantation and other affected communities remain hopeful and determined to rebuild stronger than ever before.
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Well, the localized apocalypse should be over soon. The Waffle House is reopening after renovations. Anyone living within FEMA Waffle House disaster scale areas will understand this.
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November 10th, 2023
Wealth inequality is a pressing issue in the United States, with disparities growing exponentially over the past few decades. While this problem is often attributed to income disparities and other societal and economic factors, the readings “After Katrina-Rebuilding Places and Lives” by Briggs and “Impacts of Natural Hazards on Wealth Inequality” by Howell & Elliott 2019 demonstrate the less explored contributors to wealth inequality: damages from natural hazards and its influence in the persistence of social inequalities. In this blog post, I will shed light on how these factors shape wealth distribution in the United States.
Author Briggs highlights in his article an often-overlooked contributor to wealth inequality – damages from natural hazards. As a junior in the sociology department, I was granted the opportunity to take a Social Stratification course taught by Sociologist Annette Laraeu. Throughout that course I learned the variety of ways in which American society is stratified, from micro (as in clothing brands and technology ecosystems like Apple and Samsung) to the macro (healthcare, education, various workplaces). I don’t recall ever covering the scale or scope of natural disasters in the United States and the further perpetuating of inequality. Briggs highlights the 2017 hurricane season, which caused over $260 billion in direct damages (Briggs, 2006). The chronic and pervasive nature of these events has significant implications for wealth inequality. The study finds that as local hazard damages increase, so too does wealth inequality, especially along the lines of race, education, and homeownership. Briggs further expands on the unexpected consequences of FEMA aid and the importance of considering the intersection of social stratification and natural hazards. “Impacts of Natural Hazards on Wealth Inequality” by Howell and Elliott, provides a broader context for wealth inequality by examining its drivers. While wealth can be accumulated through income, investments, and intergenerational transfers, the study focuses on the unequal returns on investments and intergenerational transfers. It reveals that the wealth potential of many middle- and low-wage workers has been stagnating or declining, resulting in an increasingly unequal distribution of wealth. Debt, especially interest rates on loans, has become another source of inequality. Subprime mortgages with high-interest rates, predominantly granted to low-income and minority homebuyers, are difficult to pay off, which lead to a widespread foreclosure during the housing crisis in the United States. Overall, it becomes evident that wealth inequality is a multifaceted issue influenced by various factors.
While the city of Philadelphia has not experienced any extreme natural disasters, it is important to recognize that it continues to be one of the most segregated cities in America. By understanding these dynamics, individuals in positions of power and influences such as the newly elected Mayor, Cherelle Parker, can make informed policy decisions and disaster response efforts aimed at reducing wealth inequality.
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Acetic acid CAS#: 64-19-7
IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data
Identification
Product NameAcetic acidIUPAC Nameacetic acid Molecular StructureCAS Registry Number 64-19-7EINECS Number200-580-7MDL NumberMFCD00036152Beilstein Registry Number506007Synonymsacetic acidethanoic acid64-19-7Ethylic acidVinegar acidAcetic acid glacialGlacial acetic acidAcetic acid, glacialMethanecarboxylic acidAcetasolEssigsaeureAcide acetiqueVinegarPyroligneous acidAzijnzuurAceticum acidumAcido aceticoOctowy kwasAci-jelHOAcethoic acidKyselina octovaAcOHAzijnzuur Ethanoic acid monomerAceticEssigsaeure Caswell No. 003Otic TridesilonOctowy kwas Acetic acid (natural)Orthoacetic acidAcide acetique Acido acetico FEMA No. 2006Kyselina octova MeCOOHOtic DomeboroAcidum aceticum glacialeAcidum aceticumCH3-COOHacetic acid-CH3CO2HUN2789UN2790EPA Pesticide Chemical Code 044001NSC 132953NSC-132953NSC-406306BRN 0506007Acetic acid, dilutedAcetic acid-17O2INS NO.260Acetic acid DTXSID5024394MeCO2HCHEBI:15366AI3-02394CH3COOHINS-260Q40Q9N063PE-26010.Methanecarboxylic acidCHEMBL539NSC-111201NSC-112209NSC-115870NSC-127175Acetic acid-2-13C,d4INS No. 260DTXCID304394E 260Acetic-13C2 acid (8CI,9CI)EthanoatShotgunMFCD00036152Acetic acid, of a concentration of more than 10 per cent, by weight, of acetic acid68475-71-8Acetic Acid-2-13C-2,2,2-d3C2:0acetyl alcoholOrlexVosol63459-47-2ACETIC-1-13C-2-D3 ACID-1 H (D)WLN: QV1ACETIC ACID (MART.)ACETIC ACID Acetic acid, >=99.7%285977-76-6FEMA Number 2006ACETIC-13C2-2-D3 ACID, 97 ATOM % 13C, 97 ATOM % DAcetic acid, ACS reagent, >=99.7%57745-60-5ACYHSDB 40CCRIS 595279562-15-5methane carboxylic acidEINECS 200-580-7Acetic acid 0.25% in plastic containerEssigsaureEthylateacetic aicdacetic-acidGlacial acetateacetic cidactic acidUNII-Q40Q9N063Pacetic -acidDistilled vinegarMethanecarboxylateAcetic acid, glacial Acetasol (TN)Acetic acid,glacialVinegar (Salt/Mix)3,3'-(1,4-phenylene)dipropiolic acidHOOCCH3546-67-8Acetic acid LC/MS GradeACETIC ACID ACETIC ACID Acetic acid, ACS reagentbmse000191bmse000817bmse000857Otic Domeboro (Salt/Mix)EC 200-580-7Acetic acid (JP17/NF)ACETIC ACID } -->
Physical Data
AppearanceTransparent ilquid,no visible impuritiesMoisture≤0.115%(m/m)Acetaldehyde≤0.030%(m/m)Permanganate Time≥30min
Melting Point, °C 16.716.616.5316.616.5 - 16.5516.5
Boiling Point, °CPressure (Boiling Point), Torr117.94760.051117.79760.014117.9118.28760.051118117.9760.051
Density, g·cm-3Measurement Temperature, °C1.04919.991.0216144.991.0270439.991.0326134.991.0384429.991.043924.991.046924.99
Description (Association (MCS))Solvent (Association (MCS))Temperature (Association (MCS)), °CPartner (Association (MCS))Adsorption isotherm25CF3 functionalized MIL-53(Al)AdsorptionC30H28N4O4AdsorptionSAPO-34Adsorptionneat (no solvent, gas phase)aluminum oxide
Spectra
Description (NMR Spectroscopy)Nucleus (NMR Spectroscopy)Solvents (NMR Spectroscopy)Temperature (NMR Spectroscopy), °C Frequency (NMR Spectroscopy), MHzChemical shifts, Spectrum13CChemical shifts, Spectrum1Hwater-d2Chemical shifts1Hheavy water400Chemical shifts1H-163.16500Chemical shifts1Hheavy water400.1
Description (IR Spectroscopy)Solvent (IR Spectroscopy)Temperature (IR Spectroscopy), °CSpectrum ATR (attenuated total reflectance), Bands, SpectrumSpectrumgas-195.16
Description (UV/VIS Spectroscopy)Solvent (UV/VIS Spectroscopy)Comment (UV/VIS Spectroscopy)SpectrumH2O175 - 350 nmSpectrum190 - 240 nmSpectrum180 - 250 nmAbsorption maxima
Route of Synthesis (ROS)
Route of Synthesis (ROS) of Acetic acid CAS 64-19-7
ConditionsYieldWith methanesulfonic acid In cyclohexane; butanone at 80℃; under 760.051 Torr; Reagent/catalyst; Temperature; Solvent; Large scale;Experimental ProcedureEsterification raw material 9.2kgGlycerin and water-carrying agent 3kg butanone were added to a 30L atmospheric pressure reaction kettle, and the esterification reaction was carried out.It is a reversible reaction and produces water. In order to increase the conversion rate, water can be used to separate water from the reaction system. The material that can be used as a water-carrying agent must react with water to produce an azeotrope so that the water is more easily distilled out, and the solubility in water is small, and in this scheme, cyclohexane is used as a water-carrying agent.In addition, methanesulfonic acid was added to the reaction vessel as a catalyst for the esterification reaction, and the reaction vessel was heated to 80 ° C as a reaction temperature, and then 6 kg of another esterification raw material acetic acid was gradually added to the reaction vessel to cause it to occur. The esterification reaction produces glycerol monoacetate and water. Moreover, the reaction can be simultaneously applied to a reflux system with a water separator, and the water phase of the lower layer is separated by a water separator to obtain an oil phase of the upper layer, wherein the target product glycerin monoacetate is contained in the oil phase.The product in the reaction system can also be subjected to purification treatment. Specifically, the obtained oil phase is separated by a rectification column, and the water-carrying cyclohexane and the unreacted esterified raw material acetic acid in the oil phase are removed by vacuum distillation, and the heavy fraction at the bottom of the bottom is obtained. Pure glycerol monoacetate, the corresponding yield of this product is as high as 89.2%.89.2%
Safety and Hazards
Pictogram(s)SignalDangerGHS Hazard StatementsH226 (99.72%): Flammable liquid and vapor H314 (99.96%): Causes severe skin burns and eye damage H318 (14.58%): Causes serious eye damage Precautionary Statement CodesP210, P233, P240, P241, P242, P243, P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P403+P235, P405, and P501(The corresponding statement to each P-code can be found at the GHS Classification page.)
Other Data
No data available
DruglikenessLipinski rules componentMolecular Weight60.0526logP-0.08HBA2HBD1Matching Lipinski Rules4Veber rules componentPolar Surface Area (PSA)37.3Rotatable Bond (RotB)0Matching Veber Rules2
Quantitative Results1 of 4,093Comment (Pharmacological Data)Bioactivities presentReferenceDerivatives of 2-(iminomethyl)amino-phenyl, their preparation, their use as medicaments and the pharmaceutical compositions containing them2 of 4,093Comment (Pharmacological Data)Bioactivities presentReferenceProcess for purifying carbon dioxide-containing gas streams3 of 4,093Comment (Pharmacological Data)Bioactivities presentReferenceSubstituted hydrazine mitomycin analogs4 of 4,093Comment (Pharmacological Data)Bioactivities presentReferenceVitamin D3 metabolites. I. Synthesis of 25-hydroxycholesterol.5 of 4,093Comment (Pharmacological Data)Bioactivities presentReferenceCob(I)alamin as catalyst. IV. Reduction of α,β-unsaturated nitriles6 of 4,093Comment (Pharmacological Data)Bioactivities presentReferencePreparation of 29-acetoxy-30-norlupan-20-one derivatives with the substituted ring C7 of 4,093Comment (Pharmacological Data)Bioactivities presentReferenceSTRUCTURE OF HELICOBASIDIN, A NOVEL BENZOQUINONE FROM HELICOBASIDIUM8 of 4,093Comment (Pharmacological Data)Bioactivities presentReferenceBile acids and steroids. XXXV. Some A-ring aromatic steriods having oxygen functions at C-16 and their pharmacological activities.9 of 4,093Comment (Pharmacological Data)Bioactivities presentReferenceStudies on telomers and oligomers of vinylene carbonate. VI. Stereoselective conversion of vinylene carbonate telomers to trans unsaturated phosphate esters and their chemical behaviors10 of 10Comment (Pharmacological Data)Bioactivities presentReferenceSubstituted cyclopropyl benzamides and pharmaceutical preparations and methods of use employing such compounds
Use PatternACETIC ACID is manufacture of vinyl acetate, acetic anhydride, acetic ester, acetate, ethyl cellulose, and chloro acetic acid. It can also be used in the field of synthetic fiber, binding agent, pharmacy, fertilizer and dyeing raw material, and in the field of plastic, rubber and printing as solvent.
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🔗 Rebuilding will be a huge and costly undertaking, governor says - Honolulu Civil Beat (Apple News).
So much being written comparing this disaster to other disasters around the world U.S.A.
Finally, someone writing about what will make the recover absolutely unique, and very very difficult.
Also delaying recovery is the fact that Maui is a less populous island in a remote island state. Robert Fenton, FEMA’s Region 9 administrator, likened the Maui fire to wildfires such as a 2018 blaze that destroyed much of the town of Paradise, California. He said the scale of destruction reminded him of the Mississippi Gulf Coast after Hurricane Katrina. But a major difference, he said, is the ability to respond. On the mainland, he said, it’s possible to quickly “muster 3,500 dump trucks” to move rubble. “I just can’t do it here,” he said.
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I’m getting incident command system certifications. Did you know you can just do them? For free? Online?
I got some ICS training when I did my EMT but no piece of paper to show for it. So today I did ICS 100 and 200 on the FEMA website. I’m going to do 700 and 800 too.
Each course is just a slideshow with occasional questions and then a 25 question multiple choice test. The slideshows are long but the structure is pretty straightforward. The goal is a consistent approach to disaster response at any scale. It takes a few hours to go through each slideshow.
Highly recommend to anyone who might have to organize anything or work as part of an organized group. It’s a very useful chain of command set up. Of course it’s most useful in a crisis—that is the point—but I use it as a reference for how to handle being in charge of anything and for working under someone else’s direction.
#so this is what I’m up to tonight. to be fair disaster management is a special interest#you don’t have to talk to anyone#you do need a FEMA student ID number but that’s not hard to get#look up FEMA SID and you can get one
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Day 206
February 24, 2023
The workday opened with a virtual FEMA All-hands meeting about transitioning applicants:
A Program Delivery Manager (PDMG) is the applicant’s primary point of contact, so when the PDMG has to leave, they must transfer the applicant to another PDMG.
The new Program Delivery Manager must be brought up to speed before taking on the applicant; this process typically takes 3-5 days for a small project and 5-7 days for a more complex project. Approval from higher-ups must be granted to transition major applicants/very large projects.
First the Program Delivery Manager will call the applicant to let them know they are being transitioned. Then an email will be sent out and a transition meeting will be held.
We reviewed the Public Assistance Program and Policy Guide. This is PA’s primary document, detailing everything from the grants process to eligibility and closeout.
FEMA leadership and the recipient may determine what types of site inspections will occur when the event is declared. The inspection types may be determined in a case-by-case basis by the applicant, Program Delivery Manager (PDMG), or Site Inspector Task Force Leader:
Physical: Typical in-person inspection. May be required for complex damage, especially that with significant environmental historic preservation concerns. The applicant representative will sign the first page and initial the others.
Virtual remote: FEMA site inspector leads site inspection over video. Must have at least two applicant representatives, as one must hold the camera and the other(s) can measure and take photos.
Virtual tabletop: Applicant completes their own inspection and provides all documentation to FEMA. The applicant must be more knowledgeable about FEMA/the grants obligation process, but has more flexibility on when they perform their inspections.
Regardless of which type of inspection is performed, each site inspection report will include a photo page, the Flood Insurance Rate Map, and the location map.
We watched a virtual site inspection recording and followed along on the site inspection report forms we were given yesterday:
Ask for GPS Coordinates, repeat back to applicant. Get name of damaged location and confirm the location in Google maps or a similar program; describe what is nearby and ask if that is correct.
Confirm that the applicant has legal responsibility for the site.
Tell the applicant to show and describe first damage. Ask the applicant the damage date and the date the site was built, and whether the date they provide is exact or an estimate.
Ask the cause of the damage and who will do the repairs and the method of repair. Ask if the damage/site will be replaced in kind or if hazard mitigation will be considered.
Obtain measurements. Note which components are damaged, as well as the construction materials. If a matching material cannot be obtained, the entire structure may be replaced; for example, if no birch is available to replace a damaged fence post, the entire fence may be replaced with the available wood type.
Instruct applicant to take photos. Take screenshots showing scale. (Any photos containing children must be censored.)
We watched a video on how to use various tape measures, then practiced taking and uploading photos to OneDrive. We downloaded the My GPS Coordinates app to our Apple devices and practiced making location maps on Google Earth. These maps should have 5 decimal places for the GPS coordinates, at least 2 labeled roads visible, and a file name format of [Applicant]_[Work Order #]_[Disaster Inventory #]_Site Map. Then we made the Flood Insurance Rate Map. This was fairly straightforward, although the search function is in the longitude, latitude format.
Some miscellaneous information we got:
If an applicant turns down hazard mitigation and the same site gets damaged again, the applicant has to pay 75% of the cost instead of the typical 25% this time.
Correspondence between FEMA inspectors and applicants and recipients are archived, and these emails can be requested via the Freedom of Information Act.
After work we got a meal, played a public assistance acronyms Kahoot, and then watched another movie together.
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And try to be succinct too because we all have lots of things to go over, UNDF funds WFP which mandates FAO through the Agriculture Development Program
ADP involves FEMA which is a FAO public private sector partnership to procure farming equipment, FEMA regroups most if not all of farming equipment makers
The role of FAO doesn’t stop there, through ADP it conducts feasibility studies with recipient countries for new farming projects of different scales in different areas of the world
Enters the public private sector of FAO with the World Bank, AfDB and others which too are involved in these studies because basically if WFP is going to fund the machines that FEMA procures, they are going to finance these farming projects
Recipient countries of these equipments and financing repay them over a given period to both WFP and the development banks involved
WFP gets its money back for financing the equipments, and the development banks cash in on their investments with recipient countries
In the end WFP repays UNDF, with profits because it is entitled to a share of the profits that ADP generates
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Trump plans to visit the town of East Palestine, Ohio, where the derailment occurred, next week, as he announced on his Truth Social platform on Saturday morning.
The Biden administration has faced anger from local residents and criticism from many elected Republicans over its response to the incident, which neither Biden nor Transportation Secretary Pete Buttigieg visited.
However, Environmental Protection Agency (EPA) administrator Michael Regan visited the site on Thursday.
The derailment on February 3 released highly toxic chemicals into the air, water, and ground, leading to significant concern about the long-term effects on the local community.
Trump shared an article on Truth Social about his planned visit to Ohio, where those affected by the derailment said: "Great people who need help, NOW!"
"Biden and FEMA said they would not be sending federal aid to announce I was going; he announced a team would and he would also be there, which is good news because we got them to say, "The people of East Palestine need help; see you on Wednesday," as I wrote in another post.
The Federal Emergency Management Agency (FEMA) confirmed on Friday that it will provide assistance to Ohio after reportedly telling Governor Mike DeWine's office that the state was not eligible for emergency help.
The White House also announced on Friday that they were "deploying a team of medical personnel and toxicologists to conduct public health testing and assessments" from the Department of Health and Human Services (HHS) and the Centers for Disease Control and Prevention (CDC).
Ohio has long been viewed as a swing state in presidential elections, though the state last voted for a Democratic candidate, Barack Obama, who won re-election.
Trump has already declared his intention to seek the Republican presidential nomination in 2024; he won Ohio in both 2016 and 2020.
Thomas Gift, founding director of the Centre on U.S. Politics at University College London, U.K., told Newsweek on Saturday that the Biden administration's approach to the East Jerusalem derailment could have political implications.
"Criticism of Biden's flat-footed response to the Ohio tragedy is well-deserved," Gift said. "Even if just as a symbolic show of support, the fact that it took a senior administration official roughly two weeks to visit the site isn't excusable given the scale and magnitude of the incident."
Gift told Newsweek that while "it's hard to talk politics in the wake of such a tragedy, it's also particularly head-scratching that the White House could be so delinquent in Ohio of all places."
"If Democrats end up losing the key swing state, there's no doubt there will be endless finger-pointing--and reasons--on who failed to see this coming," Gift added.
President Biden's administration has defended its response amid the criticism, saying it "mobilized a robust, multi-agency effort to support the people of East Palestine, Ohio."
Then, Regan, the cabinet has yet to visit East Palestine in the wake of the derailment.
East Palestine Mayor Trent Conaway told a community meeting this week that it took almost two weeks for anyone in the White House to contact him. Republican Senator J.D. Vance pushed back against Buttigieg's comments about the Trump administration loosening train safety rules.
"Stop blaming Donald Trump, a guy who hasn't been president for three years, and use the federal government to do the things necessary to help people in this community," Vance said.
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